By Ray A. Dickie, S. S. Labana, Ronald S. Bauer
content material: Cross-linking and constitution of polymer networks / Karel Dusek and William J. MacKnight --
Intramolecular response : results on community formation and homes / R.F.T. Stepto --
Selective quenching of large-scale molecular motions by means of cross-linking within the strained kingdom / Ole Kramer --
Rubber elasticity modulus of interpenetrating heteropolymer networks / Christos Tsenoglou --
Star-branched nylon 6 : results of branching and cross-linking on polymer houses / Lon J. Mathias and Allison M. Sikes --
community formation and degradation in urethane and melamine-formaldehyde cross-linked coatings / David R. Bauer --
impact of ionizing radiation on an epoxy structural adhesive / Thomas W. Wilson, Raymond E. Fornes, Richard D. Gilbert, and Jasper D. reminiscence --
Frequency-dependent dielectric research : tracking the chemistry and rheology of thermosets in the course of medication / D. Kranbuehl, S. Delos, M. Hoff, L. Weller, P. Haverty, and J. Seeley --
functionality features of the fluorescence optrode treatment sensor / R.L. Levy and S.D. Schwab --
Deformation kinetics of cross-linked polymers / T.S. Chow --
Plastic deformation in epoxy resins / S.M. Lee --
Fractoemission from epoxy and epoxy composites / J.T. Dickinson and A.S. Crasto --
Fatigue habit of acrylic interpenetrating polymer networks / Tak Hur, John A. Manson, and Richard W. Hertzberg --
homes of epoxy resins cured with ring-alkylated m-phenylene diamines / Robson F. Storey, Sudhakar Dantiki, and J. Patrick Adams --
Cross-linking of an epoxy with a combined amine as a functionality of stoichiometry : dynamic mechanical spectroscopy reviews / D. Wingard, W. Williams, ok. Wolking, and C.L. Beatty --
Thermal pressure improvement in thick epoxy coatings / D. King and J.P. Bell --
Recycling of cured epoxy resins / Conchita V. Tran-Bruni and Rudolph D. Deanin --
Semiinterpenetrating networks in line with triazine thermoset and N-alkylamide thermoplastics / J.A. Feldman and S.J. Huang --
improvement of multiphase morphology in sequential interpenetrating polymer networks / J.H. An and L.H. Sperling --
Polyurethane-acrylic coatings : interpenetrating polymer networks / H.X. Xiao, K.C. Frisch, P.I. Kordomenos, and R.A. Ryntz --
Ionomer interpenetrating polymer community coatings from polyurethane and vinyl chloride copolymer / H.X. Xiao, K.C. Frisch, and S. Al-Khatib --
Liquid crystalline oligoester diols as thermoset coatings binders / Adel F. Dimian and Frank N. Jones --
Synthesis of cross-linkable heterogeneous oligoester diols through direct esterification with p-hydroxybenzoic acid : use in coatings binders / Daozhang Wang and Frank N. Jones --
Benzocyclobutene in polymer synthesis : novel cross-linking structures derived from a bisbenzocyclobutene and bismaleimides, dicyanates, and bisphenylacetylenes / Loon Seng Tan, Edward J. Soloski, and Fred E. Arnold --
Characterization of bisbenzocyclobutene high-temperature resin and bisbenzocyclobutene combined with a suitable bismaleimide resin / Lisa R. Denny, Ivan J. Goldfarb, and Michael P. Farr --
Carbon-13 NMR research of the oligomerization of bismaleimidodiphenyl methane with diallyl bisphenol A / Keith R. Carduner and Mohinder S. Chattha --
Characterization of cobalt(II) chloride-modified condensation polyimide movies : houses sooner than and after solvent extraction / J.D. Rancourt and L.T. Taylor --
Chain cross-linking photopolymerization of tetraethyleneglycol diacrylate : thermal and mechanical research / J.G. Kloosterboer and G.F.C.M. Lijten --
constitution and homes of polydimethacrylates : dental functions / D.T. Turner, Z.U. Haque, S. Kalachandra, and Thomas W. Wilson --
Monomer interplay : results on polymer therapy / Jose' A. Ors, Ivan M. Nunez, and L.A. Falanga --
Amide-blocked aldehyde-functional monomers : synthesis and chemistry / R.K. Pinschmidt, Jr., W.F. Burgoyne, D.D. Dixon, and J.E. Goldstein --
Amide-blocked aldehyde-functional monomers : cross-linkable substrate-reactive copolymers / R.K. Pinschmidt, Jr., G.E. Davidowich, W.F. Burgoyne, D.D. Dixon, and J.E. Goldstein.
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Additional resources for Cross-Linked Polymers. Chemistry, Properties, and Applications
Cross-Linking and Structure of Networks 27 Konak, C . ; Tuzar, Z . ; Dusek, K. Polym. B u l l . , in press. ; Dusek, K. Polymer 1983, 24 981. ; Dusek, K. Polym. Bull. 1982 8 359. ; Lunak, S. J r . , Editors. W. de Gruyter, Berlin 1987, p. 269. ; Matejka, L. ; Kahovec, J . Editors. W. De Gruyter, Berlin, 1987, p. 279. ; Dusek, K. Macromolecules 1986, 19, 2139. A. Polym. Commun. 1985, 26, 55. Rigbi, Z . E. J . Polym. S c i . , Polym. Phys. Ed. 1986, 24, 443. , Helmis, G. Adv. Polym. Sci. 1987, in press.
9. Copyright 1985 O. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1988. 3. KRAMER Selective Quenching of Large-Scale Molecular Motions 2 9 1 0 0 0 which e x h i b i t s a much narrower p l a t e a u zone than t h a t shown i n F i g u r e 1 . I t can be seen t h a t the t e r m i n a l zone has d i s a p p e a r e d i n the case o f the c r o s s - l i n k e d sample. I t means t h a t the m o l e c u l a r motions r e s p o n s i b l e f o r t e r m i n a l r e l a x a t i o n have been quenched by the c r o s s - l i n k s .
I f i t i s t r u e t h a t r e p t a t i o n (2) i s r e s p o n s i b l e f o r t h e d e c r e a s e o f modulus i n the t e r m i n a l zone, the o b s e r v e d b e h a v i o r i n d i c a t e s e i t h e r t h a t the r e p t a t i o n p r o c e s s i s s t r a i n dependent o r t h a t an a d d i t i o n a l r e l a x a t i o n p r o c e s s becomes important a t l a r g e s t r a i n s . The l a t t e r p o s s i b i l i t y has l e d t o the p r o p o s a l o f a new type of m o l e c u l a r motion by D o i and Edwards ( 3 ) .