By Ayyalusamy Ramamoorthy
Over the last decade, a myriad of recommendations have proven that solid-state nuclear magnetic resonance (NMR) can be utilized in a large spectrum of functions with highly awesome effects. Solid-state NMR effects can yield high-resolution info at the constitution and serve as of many vital organic solids, together with viruses, fibril-forming molecules, and molecules embedded within the mobile membrane. Filling a void within the present literature, NMR Spectroscopy of organic Solids examines the entire fresh advancements, implementation, and interpretation of solid-state NMR experiments and some great benefits of making use of them to organic structures. The booklet emphasizes how those concepts can be utilized to achieve the constitution of non-crystalline structures of any measurement. It explains how those isotropic and anisotropic couplings interactions are used to figure out atomic-level constructions of organic molecules in a non-soluble nation and extrapolate the 3-dimensional constitution of membrane proteins utilizing magic-angle spinning (MAS). The publication additionally makes a speciality of using multidimensional solid-state NMR equipment within the research of aligned platforms to supply easy information regarding the mechanisms of motion of numerous biologically lively molecules. Addressing rules, equipment, and functions, this publication presents a serious choice of solid-state NMR tools for fixing quite a lot of functional difficulties that come up in either educational and business study of biomolecules within the stable nation. NMR Spectroscopy of organic Solids is a forward-thinking source for college kids and researchers in analytical chemistry, bioengineering, fabric sciences, and structural genomics
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Additional info for NMR spectroscopy of biological solids
133. S. , C-13-C-13 rotational resonance width distance measurements in uniformly C-13-labeled peptides, J. Am. Chem. , 125, 15623, 2003. 134. , Uchida, K. , Determination of the complete structure of a uniformly labeled molecule by rotational resonance solid-state NMR in the tilted rotating frame, J. Am. Chem. , 121, 4064, 1999. 135. , Uchida, K. , Three-dimensional structure determination of a uniformly labeled molecule by frequency-selective dipolar recoupling under magic-angle spinning, J. Biomol.
118, 8873, 2003. 116. T. , Frequency-selective heteronuclear dephasing by dipole couplings in spinning and static solids, J. Chem. , 105, 10289, 1996. 117. , Herzfeld, J. , Measurement of C-13-N-15 distances in uniformly C-13 labeled biomolecules: J-decoupled REDOR, J. Am. Chem. , 121, 10237, 1999. 118. , Herzfeld, J. , Frequency selective heteronuclear dipolar recoupling in rotating solids: accurate C-13-N-15 distance measurements in uniformly C-13,N-15-labeled peptides, J. Am. Chem. , 123, 3507, 2001.
Magn. , 81, 196, 1989. 14. , Vega, S. , Transferred-echo double-resonance NMR, J. Magn. , 96, 205, 1992. 15. H. , Rotational resonance in solid state NMR, Chem. Phys. , 146, 71, 1988. 16. , Creuzet, F. , Theory and simulations of homonuclear spin pair systems in rotating solids, J. Chem. , 92, 6347, 1990. 17. G. , Chemical shift correlation spectroscopy in rotating solids: radio-frequency dipolar recoupling and longitudinal exchange, J. Chem. , 96, 8624, 1992. 18. J. , Double-quantum homonuclear rotary resonance: efficient dipolar recovery in magic-angle spinning nuclear magnetic resonance, J.