By Guangshan Zhu, Hao Ren
This booklet describes the layout, synthesis, characterization and functions of porous natural frameworks (POFs). exact emphasis is put on the usage of porous fabrics for CO2 seize and CH4 and H2 garage, that have promising power for addressing the problems of environmental degradation and weather switch. it is usually chapters introducing the homes of POFs and defining the foundations of synthesis, in addition to a bankruptcy facing post-modified POFs. This e-book is meant for these readers who're attracted to porous fabrics and their applications.
Guangshan Zhu is a professor on the university of Chemistry, Jilin collage, China.
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Additional info for Porous Organic Frameworks: Design, Synthesis and Their Advanced Applications
12 Synthetic route for sulfonate functionalized PPNs. Chlorosulfonic acid or concentrated sulfonic acid could be used for the sulfonation reaction. Reprinted with permission from Ref. . 13 Synthetic route to polyamine-tethered PPNs. Reproduced from Ref.  by permission of John Wiley & Sons Ltd. 2 Poly-amine Substitution of PAF-1 Additionally, the same group prepared a family of poly-amine substituted PAF-1 to obtain adsorbents with high CO2 capacity and selectivity . First, PAF-1 was performed chloromethylation using CH3COOH/HCl/H3PO4/HCHO system.
Xiang Z, Cao D (2012) Synthesis of luminescent covalent-organic polymers for detecting nitroaromatic explosives and small organic molecules. Ren H, Ben T, Sun F et al (2011) Synthesis of a porous aromatic framework for adsorbing organic pollutants application. Kassab R, Jackson K, El-Kadri O et al (2011) Nickel-catalyzed synthesis of nanoporous organic frameworks and their potential use in gas storage applications. Kuhn P, Forget A, Su D et al (2008) From microporous regular frameworks to mesoporous materials with ultrahigh surface area: dynamic reorganization of porous polymer networks.
As simplified symmetry notation, these 2D or 3D monomers are referred to as 2D-C2, 2D-C3, 2D-C4, and 3D-Td. Through carefully analyzing the geometry of monomers and the constructing reactions, the forming process of COFs could be discussed in detail. (1) Along with the reactions occur new types of connection forms; (2) the topological structures do not change during bond formation. Regarding (1), the reactions of borate anhydride formation and ZnCl2 mediated nitrile cyclotrimerization could offer newly formed triangular connections.